亚洲男人在线网_欧美永久视频_欧美久久特级黄色_996热在线播放_www黄色视频在线观看_久久一本久综合_牛牛影视二区_久久久久久北条麻妃_国产精品精品在线不卡_色婷婷狠狠五月综合天色拍_青娱乐最新欧美视频_麻豆美女黄片_欧美日韩主播国产_亚洲天堂入口_蜜桃狠狠色伊人97

產(chǎn)品詳情

  • 產(chǎn)品名稱：PDBPyBT (DPPDPyBT, high-mobility n-type polymer)

  • 產(chǎn)品型號：PDBPyBT (DPPDPyBT, high-mobility n-type polymer)
  • 產(chǎn)品廠商：Ossila
  • 產(chǎn)品價格：0
  • 折扣價格：0
  • 產(chǎn)品文檔：
你添加了1件商品 查看購物車
簡單介紹：
PDBPyBT (DPPDPyBT, high-mobility n-type polymer)
詳情介紹：
Batch Mw Mn PDI
M321 20,310 12,030 1.69
M322 750,909 157,538 4.77
M323 ≥30,000 ≤3


 

General Information

CAS number 1455028-36-0
Chemical formula (C64H92N4O2S2)n
HOMO / LUMO HOMO = 5.69 eV, LUMO = 4.33 eV [1]
Synonyms
  • Poly(2,5-bis(2-octyldodecyl)-3,6-di(pyridin-2-yl)-pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-alt-2,2’-bithiophene)
  • PDBPyBT
  • DPP-DPyBT
Suggesting solvents Dichlorobenzene at elevated temperature ca. 110 °C
Classification / Family Pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione, Bithiophene, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells, OFETs, All-polymer solar cells.

 

dppdpybt, PDBPyBT, 1455028-36-0, chemical structure  
Chemical structure and product image of Poly(2,5-bis(2-octyldodecyl)-3,6-di(pyridin-2-yl)-pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-alt-2,2’-bithiophene) (DPPDPyBT). 

Applications

Poly(2,5-bis(2-octyldodecyl)-3,6-di(pyridin-2-yl)-pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-alt-2,2’-bithiophene) (DPPDPyBT) is a good electron transporting materials used in the application of OFETs and OPVs.

DPPDPyBT contains a DPP unit which has been found to be an excellent electron accepting moiety for a large number of polymer semiconductors for OTFTs, OPVs and OLEDs. DPPDPyBT has been proven to have a planar structure, together with two five-membered rings having six π-electrons being shared, an electron rich moiety with DPP and two pyridyl units being excellent electron withdrawing ability, resulting in DPPDPyBT being an excellent candidate as an electron transporting material.

As one of promising high charge carrier mobility polymers (electron and hole mobility up to 6.3 cm2V-1s-1 and 2.78cm2V-1s-1 respectively, has been reported [1]), these type of polymers are also used as blending material (low ratio) for OPV devices to facilitate electron collection from the active layer to PCBMs [2].

 

Synthetic Route

PDBPyBT was synthesised engaging Stille Coupling reaction with 3,6-Bis(5-bromopyridin-2-yl)-2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione and 5,5′-bis(trimethylstannyl)-2,2-bithiophene as starting materials in chlorobenzene as solvent. Polymer was purified by Soxhlet extraction with methanol, acetone, hexane and chlorobenzene as washing and extracting solvents.

synthesis of DPPDPyBT
PDBPyBT synthesise engaging Stille Coupling reaction with 3,6-di(5-bromopyridin-2-yl)-2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione and 5,5-bis(trimethylstannyl)-2,2-bithiophene as starting materials.

 

Literature and Reviews

  1. Record High Electron Mobility of 6.3 cm2V-1s-1 Achieved for Polymer Semiconductors Using a New Building Block, B. Sun et al., Adv. Mater., 26, 2636-2642 (2014)
  2. Enhanced efficiency of polymer solar cells by adding a high-mobility conjugated polymer, S. Liu et al., Energy Environ. Sci., 8, 1463-1470 (2015)
  3. A pyridine-flanked diketopyrrolopyrrole (DPP)-based donor–acceptor polymer showing high mobility in ambipolar and n-channel organic thin film transistors, B. Sun, Polym. Chem., 6, 938-945 (2015)

 

在線客服